Molecularly imprinted polymers for selective extraction of crystal violet from natural seawater coupled with high-performance liquid chromatographic determination     

LIAN Ziru  and WANG Jiangtao 《中国海洋大学学报(英文版)》2014,13(2):236-242

Molecularly imprinted polymers(MIPs) were prepared by the bulk polymerization using crystal violet as the template molecule, and the methacrylic acid and ethylene glycol dimetheacrylate as functional monomer and cross-linker, respectively. Systematic investigations of synthetic conditions were conducted. The surface morphology and recognition mechanism of the obtained polymers were studied using scanning electron microscope and spectrophotometric analysis. MIPs showed high affinity to template molecule and were successfully applied as special solid-phase extraction sorbent for selective extraction of crystal violet from natural seawater. An off-line molecularly imprinted solid-phase extraction(MISPE) method followed by high-performance liquid chromatography with diodearray detection for the analysis of crystal violet was also established. MISPE columns have good recoveries for crystal violet standard solutions and good linearity was obtained over the concentration range of 0-200 μg L-1(R2 0.99). Finally, two natural seawater samples were investigated. The recoveries of spiked seawater on the MISPE columns were from 44.47% to 62.34%, the relative standard deviation(n=3) being in the range of 2.89%-5.96%.  相似文献   

Uplift of symmetrical anchor plates by using grid-fixed reinforced reinforcement in cohesionless soil     

Hamed Niroumand  Khairul Anuar Kassim 《中国海洋工程》2014,28(1):115-126

Uplift response of symmetrical anchor plates with and without grid fixed reinforced （GFR） reinforcement was evaluated in model tests and numerical simulations by Plaxis. Many variations of reinforcement layers were used to reinforce the sandy soil over symmetrical anchor plates. In the current research, different factors such as relative density of sand, embedment ratios, and various GFR parameters including size, number of layers, and the proximity of the layer to the symmetrical anchor plate were investigated in a scale model. The failure mechanism and the associated rupture surface were observed and evaluated. GFR, a tied up system made of fiber reinforcement polymer （FRP） strips and end balls, was connected to the geosynthetic material and anchored into the soil. Test results showed that using GFR reinforcement significantly improved the uplift capacity of anchor plates. It was found that the inclusion of one layer of GFR, which rested directly on the top of the anchor plate, was more effective in enhancing the anchor capacity itself than other methods. It was found that by including GFR the uplift response was improved by 29%. Multi layers of GFR proved more effective in enhancing the uplift capacity than a single GFR reinforcement. This is due to the additional anchorage provided by the GFR at each level of reinforcement. In general, the results show that the uplift capacity of symmetrical anchor plates in loose and dense sand can be significantly increased by the inclusion of GFR. It was also observed that the inclusion of GFR reduced the requirement for a large L/D ratio to achieve the required uplift capacity. The laboratory and numerical analysis results are found to be in agreement in terms of breakout factor and failure mechanism pattern.  相似文献   

聚合物钻井液在河北广宗勘探区深孔施工中的应用     

孙贵生 《中国煤炭地质》2014,(6):71-73

在河北广宗勘探区深孔施工中,由于地表钻探用水水质影响及原钻井液体系不合适,造成钻井液性能指标达不到要求,性能难以控制,尤其失水量严重超标,接连发生孔内事故。针对存在的问题,经过分析和实验,采用化学方法处理钻探用水,选用聚合物钻井液,解决了深部钻孔施工存在的难点,收到了较好的效果,单孔深度达到1937.35m,并刷新了本单位及局属单位的钻探记录。  相似文献   

玻璃纤维增强聚合物抗浮锚杆抗拔性能试验研究与机制分析   总被引：1，自引：0，他引：1  

张明义  寇海磊  白晓宇 《岩土力学》2014,35(4):1069-1076

抗浮锚杆作为一种竖向锚固技术在我国许多地区广泛应用,锚杆作为抗浮结构的核心其性能受到极大关注。但因钢材易腐蚀,传统金属锚杆的耐久性受到质疑,特别是地铁等地下工程存在杂散电流,限制了金属抗浮锚杆的应用。玻璃纤维增强聚合物(GFRP)抗浮锚杆是一种由树脂基体和玻璃纤维复合而成的新材料,与金属锚杆相比,它具有耐腐蚀、抗拉强度高、自重轻等优良特性。通过植入式裸光纤传感测试技术对GFRP抗浮锚杆的界面应力分布、荷载传递规律及破坏机制进行了研究,论证了GFRP抗浮锚杆使用的适宜性。试验表明,GFRP抗浮锚杆破坏以杆体基体材料剪切破坏为主,?28 mm锚杆极限抗拔力为250 kN,能够满足工程需要;杆体轴力沿深度方向逐渐递减,并且超过一定长度后杆体不再受力。结果显示,中风化岩地区,当锚固段长度为3.95⁶.95 m时,轴力影响深度范围约为3.7 m,说明GFRP抗浮锚杆同样存在临界锚固深度问题。锚杆界面剪应力呈不均匀分布,剪应力峰值随荷载的增加逐渐向下转移,同时0值点也向杆体深部转移。研究成果可为GFRP抗浮锚杆应用于工程实际提供依据。  相似文献   

高聚物外包盾构隧道离心机振动台试验研究     

马雪  王复明  郭成超  张继春 《地震工程与工程振动》2022,42(1):180-187

为了验证非水反应聚氨酯高聚物(后文简称高聚物)外包盾构隧道具有减震性能,对高聚物外包盾构隧道模型和无外包隧道模型,采用离心机振动台进行对比试验。针对中密砂土围岩,在不同阵型特征的地震波输入下,对比有无高聚物外包隧道加速度、频谱、隧道动力响应和地表沉降,分析高聚物的减震性能。试验结果表明:在不同地震激励的工况下,对于有无高聚物外包的隧道模型,其加速度和频谱差别不大;二者隧道各点上的动应变平均相差31.32%;高聚物外包层隧道模型地表的最终沉降分别比无外包隧道模型和自由场地表沉降约小20%和50%。试验证明高聚物对盾构隧道有减震作用,此试验研究为高聚物在今后的工程应用提供参考依据。  相似文献   

Drilling Technology of the M-1 Well in Hot Dry Rock of Matouying,Tangshan北大核心CSCD   总被引：1，自引：0，他引：1  

张云  高亮  刘现川  赵岩  王德  张建永 《地质与勘探》2022,58(1):176-186

This paper presents the general situation and key techniques of the drilling well M-1 in Matouying dry hot rock exploration hole, Leting, Tangshan, Hebei Province. A series of problems have been studied on the sea water drilling fluid, high temperature resistant fresh water drilling fluid, screw composite drilling technique, screw hole coring technology, and high temperature, thus solving the difficulty of sea water drilling fluid well protection, poor stability of drilling fluid under high temperature, and low efficiency in hot dry rock drilling and coring drilling to ensure the safety of the borehole and improve drilling efficiency. The high temperature resistant double condensation and double density cement slurry system and relevant technical measures are adopted to ensure the quality of cementing in the high temperature environment. Through the understanding and analysis of the strata in this area, this work provides valuable experience for drilling in the same strata in the future. The final hole depth of the M-1 well in Matouying is 4502. 11m, and hot dry rock with a temperature of 150t is found at 3965 m, which is the first hot dry rock well with a temperature of more than 150°C in the Beijing-Tianjin-Hebei region so far. © 2022 Editorial Board of Geology and Exploration. All rights reserved.  相似文献   

凝胶堵漏技术在阳山矿区漏失地层中的应用          下载免费PDF全文

石立明  曹灶开 《探矿工程》2015,42(9):22-24,29

甘肃省文县阳山矿区地质构造复杂,地层破碎蚀变强烈,多层位漏失,钻探施工漏失现象普遍。在研究地层漏失机理的基础上试验应用了聚合物凝胶堵漏技术。ZK2232孔的现场应用表明,聚合物凝胶堵漏剂与其他惰性桥堵剂配合使用,能很好地解决钻进过程中的恶性漏失问题,堵漏效果较好。在堵漏施工中,聚合物凝胶堵漏不受漏失通道的限制,能够通过挤压变形进入裂缝和孔洞空间,最终达到封堵漏层的目的。  相似文献   

煤田地质超深孔钻探工艺     

孙贵生  张纯峰 《中国煤炭地质》2015,(1):57-61

在对深部煤田地质钻孔钻进工艺研究的基础上,有针对性选择使用聚合物泥浆,解决了基浆配制用水及泥浆抗地表水水质污染问题。通过改变双管钻具长度和改换取心钻头的切削具,满足软硬互层对钻头钻进效率的影响。在煤系地层钻进中,除采用常规的单管钻具钻进外,在见煤预告下过后,采用加长双管取心钻具,既可保证了回次进尺,又可保证岩心的采取。多项措施落实,不仅解决了生产中的一些难题,收到了较好的效果,而且创造了河北省煤田地质局煤田地质单孔钻探深度2 009.12m的新纪录,为今后深部钻孔的施工积累了经验。  相似文献   

CFRP布约束增强高强混凝土柱抗震性能数值分析     

王苏岩  ;曹怀超  ;徐振清 《地震学刊》2014,(6):712-717

采用地震工程开源模拟软件OpenSees（Open System for Earthquake Engineering Simulation）对CFRP（Carbon Fiber Reinforced Polymer,碳纤维增强复合材料）布加固高强钢筋混凝土方柱的抗震性能进行了数值分析。采用Steel02Material和Concrete02Material材料本构模型模拟了CFRP布加固高强混凝土方柱的抗震性能;在此基础上,进一步研究了轴压比和剪跨比这2个因素对试件抗震性能的影响。将所得数值分析结果与相同条件下的试验结果对比后发现：基于Steel02 Material和Concrete02 Material材料本构,利用OpenSees,可以较好地模拟CFRP布加固高强混凝土方柱的抗震性能,并且与试验结果（滞回曲线、骨架曲线、水平承载力和位移延性系数）能够较好地吻合,从而说明该数值分析方法还可以准确地反映出轴压比和剪跨比对高强混凝土柱抗震性能的影响规律。  相似文献   

基于性能的碳纤维抗震加固设计   总被引：2，自引：1，他引：1  

胡孔国  陈小兵  岳清瑞 《地震工程与工程振动》2004,24(5):159-166

本文探讨了基于性能的加固设计的基本思路和设计过程,并给出了一个基于性能的碳纤维加固设计的工程实例,采用pushover静力推覆分析的方法分析对比了结构加固前后的性能,表明原结构的抗震性能不足,经碳纤维加固后的结构抗震性能明显提高,满足8度抗震设防烈度要求。  相似文献